MARC details
| 000 -LEADER |
|---|
| fixed length control field |
02799cam a2200313 a 4500 |
| 003 - CONTROL NUMBER IDENTIFIER |
|---|
| control field |
EG-GiCUC |
| 008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION |
|---|
| fixed length control field |
160521s2015 ua d f m 000 0 eng d |
| 040 ## - CATALOGING SOURCE |
|---|
| Original cataloging agency |
EG-GiCUC |
| Language of cataloging |
eng |
| Transcribing agency |
EG-GiCUC |
| 041 0# - LANGUAGE CODE |
|---|
| Language code of text/sound track or separate title |
eng |
| 049 ## - LOCAL HOLDINGS (OCLC) |
|---|
| Holding library |
Deposite |
| 097 ## - Thesis Degree |
|---|
| Thesis Level |
M.Sc |
| 099 ## - LOCAL FREE-TEXT CALL NUMBER (OCLC) |
|---|
| Classification number |
Cai01.12.09.M.Sc.2015.Am.P |
| 100 0# - MAIN ENTRY--PERSONAL NAME |
|---|
| Personal name |
Amira Mohamed Abdelwahab |
| 245 10 - TITLE STATEMENT |
|---|
| Title |
Physico chemical studies on dimethyltin (IV) complexes with homopiperazine : |
| Remainder of title |
Synthesis and equilibrium study / |
| Statement of responsibility, etc. |
Amira Mohamed Abdelwahab ; Supervised Mohamed Mohamed Shoukry , Mohamed Refaat Shehata |
| 246 15 - VARYING FORM OF TITLE |
|---|
| Title proper/short title |
الثنائى الميثيل مع هوموبيرازين (IV) {uFEA9}{uFEAD}{uFE8D}{uFEB3}{uFE8E}{uFE95} {uFED3}{uFEF4}{uFEB0}{uFEF3}{uFEEE}{uFEDB}{uFEF4}{uFEE4}{uFEF4}{uFE8E}{uFE8B}{uFEF4}{uFE94} {uFECB}{uFEE0}{uFEF0} {uFEE3}{uFE98}{uFEAE}{uFE8D}{uFEDB}{uFE92}{uFE8E}{uFE95} {uFE8D}{uFEDF}{uFED8}{uFEBC}{uFEAA}{uFEF3}{uFEAE} : |
| Remainder of title |
{uFE97}حضير {uئإإؤ} {uئإء٩}{uئإءؤ}{uئإ٨ؤ}{uئإآ٣}{uئإ٩٤} {uئإ٨٧}تز{uئإ٨ؤ}{uئإإ٥} |
| 260 ## - PUBLICATION, DISTRIBUTION, ETC. |
|---|
| Place of publication, distribution, etc. |
Cairo : |
| Name of publisher, distributor, etc. |
Amira Mohamed Abdelwahab , |
| Date of publication, distribution, etc. |
2015 |
| 300 ## - PHYSICAL DESCRIPTION |
|---|
| Extent |
138 P. : |
| Other physical details |
charts ; |
| Dimensions |
25cm |
| 502 ## - DISSERTATION NOTE |
|---|
| Dissertation note |
Thesis (M.Sc.) - Cairo University - Faculty of Science - Department of Inorganic Chemistry |
| 520 ## - SUMMARY, ETC. |
|---|
| Summary, etc. |
The thesis involves the synthesis and characterization of dimethyltin (IV) complexes with homopiperazine (HPIP). The composition and the structure of the complexes are investigated by elemental analysis, IR, NMR, mass spectra and thermal analysis measurements. The complexes formed are 1 : 1 stoichiometry. Protonation equilibria of the ligands, hydrolysis of dimethyltin(IV) and their complex formation equilibrium constants were determined at different temperatures and in dioxane water solutions of different composition. The thermodynamic parameters, {u2206}H{u00B0}, {u2206}S{u00B0} and {u2206}G{u00B0} of homopiperazine complexes were determined in aqueous solution. The formation of ternary complexes of homopiperazine and dimethyltin(IV) with DNA constituents were investigated. The kinetic and thermodynamic parameters of thermal degradation process have been calculated using coats redfern and horowitz metzger methods. Density functional theory (DFT) calculations have been carried out to investigate the equilibrium geometry of the ligand and DMT - HPIP complex at the B3LYP / 6 - 311G (d) and B3LYP / LANL2DZ level of theory, respectively, using gaussian 09 program. The biological activities were investigated |
| 530 ## - ADDITIONAL PHYSICAL FORM AVAILABLE NOTE |
|---|
| Additional physical form available note |
Issued also as CD |
| 653 #4 - INDEX TERM--UNCONTROLLED |
|---|
| Uncontrolled term |
Dimethyltin (IV) complexes |
| 653 #4 - INDEX TERM--UNCONTROLLED |
|---|
| Uncontrolled term |
Formation equilibria |
| 653 #4 - INDEX TERM--UNCONTROLLED |
|---|
| Uncontrolled term |
Homopiperazine |
| 700 0# - ADDED ENTRY--PERSONAL NAME |
|---|
| Personal name |
Mohamed Mohamed Shoukry , |
| Relator term |
|
| 700 0# - ADDED ENTRY--PERSONAL NAME |
|---|
| Personal name |
Mohamed Refaat Shehata , |
| Relator term |
|
| 905 ## - LOCAL DATA ELEMENT E, LDE (RLIN) |
|---|
| Cataloger |
Nazla |
| Reviser |
Revisor |
| 905 ## - LOCAL DATA ELEMENT E, LDE (RLIN) |
|---|
| Cataloger |
Samia |
| Reviser |
Cataloger |
| 942 ## - ADDED ENTRY ELEMENTS (KOHA) |
|---|
| Source of classification or shelving scheme |
Dewey Decimal Classification |
| Koha item type |
Thesis |
