Synthesis and characterization of schiff bases metal complexes derived from some diamine compounds / (Record no. 79148)
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| 000 -LEADER | |
|---|---|
| fixed length control field | 03208cam a2200337 a 4500 |
| 003 - CONTROL NUMBER IDENTIFIER | |
| control field | EG-GiCUC |
| 005 - DATE AND TIME OF LATEST TRANSACTION | |
| control field | 20250223032641.0 |
| 008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION | |
| fixed length control field | 201207s2020 ua d f m 000 0 eng d |
| 040 ## - CATALOGING SOURCE | |
| Original cataloging agency | EG-GiCUC |
| Language of cataloging | eng |
| Transcribing agency | EG-GiCUC |
| 041 0# - LANGUAGE CODE | |
| Language code of text/sound track or separate title | eng |
| 049 ## - LOCAL HOLDINGS (OCLC) | |
| Holding library | Deposite |
| 097 ## - Thesis Degree | |
| Thesis Level | Ph.D |
| 099 ## - LOCAL FREE-TEXT CALL NUMBER (OCLC) | |
| Classification number | Cai01.12.09.Ph.D.2020.Ah.S |
| 100 0# - MAIN ENTRY--PERSONAL NAME | |
| Personal name | Ahmed Magdi Ahmed Refat Sayed |
| 245 10 - TITLE STATEMENT | |
| Title | Synthesis and characterization of schiff bases metal complexes derived from some diamine compounds / |
| Statement of responsibility, etc. | Ahmed Magdi Ahmed Refat Sayed ; Supervised Gehad Genidy Mohamed , Walaa Hamed Mahmoud |
| 246 15 - VARYING FORM OF TITLE | |
| Title proper/short title | تحضير وتوصيف متراكبات قواعد شيف الفلزية المشتقة من بعض مركبات ثنائية الامين |
| 260 ## - PUBLICATION, DISTRIBUTION, ETC. | |
| Place of publication, distribution, etc. | Cairo : |
| Name of publisher, distributor, etc. | Ahmed Magdi Ahmed Refat Sayed , |
| Date of publication, distribution, etc. | 2020 |
| 300 ## - PHYSICAL DESCRIPTION | |
| Extent | 209 P. : |
| Other physical details | charts ; |
| Dimensions | 25cm |
| 502 ## - DISSERTATION NOTE | |
| Dissertation note | Thesis (Ph.D.) - Cairo University - Faculty of Science - Department of Inorganic Chemistry |
| 520 ## - SUMMARY, ETC. | |
| Summary, etc. | A total of eight new metal complex derivatives of 4,4'-((1Z,1'Z)-(naphthalene-1,8-diylbis(azanylylidene))bis(methanylylidene))dibenzaldehyde, H2L with the metal ions Cr(III), Mn(II), Fe(III), Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) have been successfully prepared in alcoholic medium. The complexes obtained are characterized quantitatively and qualitatively by using micro elemental analysis, conductivity measurements, FT-IR spectroscopy, UV{u2013}Vis spectroscopy, mass spectroscopy, 1HNMR, magnetic susceptibility, thermal (TG/DTG) and SEM data to illuminate their structures. The data showed that the complexes had composition of MH2L type. From the spectral study, all the complexes obtained as monomeric structure and the metals center moieties are six-coordinated with an octahedral geometry. 1H NMR spectral data of the ligand (H2L) and its Zn(II) and Cd(II) complexes agreed well with the proposed structures. Thermogravimetric data (TG and DTG) were also studied. SEM analysis confirm the nano-structures of the ligand and some of its complexes. The preliminary in vitro antibacterial and antifungal screening activity revealed that complexes showed moderate activity against tested bacterial strains and slightly higher compared to the ligand (H2L). Anticancer activity of the ligand and its metal complexes were evaluated in human cancer (MCF-7 cells viability).The IC50 of the cadmium complex is 17.6 mg/mL, which revealed its high activity. The binding between H2L with receptors of crystal structure of S. aureus (PDB ID: 3Q8U), crystal structure of sialidase NanC of Streptococcus pneumoniae (4YW4), receptors of breast cancer mutant oxidoreductase (PDB ID: 3HB5) and crystal structure of Escherichia coli (PDB ID: 3T88) were expected and set in details using molecular docking. The data showed that the most effective binding energy with 3Q8U receptor which is -11.3 kcal/mol |
| 530 ## - ADDITIONAL PHYSICAL FORM AVAILABLE NOTE | |
| Additional physical form available note | Issued also as CD |
| 653 #4 - INDEX TERM--UNCONTROLLED | |
| Uncontrolled term | 1,8-diaminonaphthalene |
| 653 #4 - INDEX TERM--UNCONTROLLED | |
| Uncontrolled term | Schiff base |
| 653 #4 - INDEX TERM--UNCONTROLLED | |
| Uncontrolled term | TG/DTG |
| 700 0# - ADDED ENTRY--PERSONAL NAME | |
| Personal name | Gehad Genidy Mohamed , |
| Relator term | |
| 700 0# - ADDED ENTRY--PERSONAL NAME | |
| Personal name | Walaa Hamed Mahmoud , |
| Relator term | |
| 856 ## - ELECTRONIC LOCATION AND ACCESS | |
| Uniform Resource Identifier | <a href="http://172.23.153.220/th.pdf">http://172.23.153.220/th.pdf</a> |
| 905 ## - LOCAL DATA ELEMENT E, LDE (RLIN) | |
| Cataloger | Nazla |
| Reviser | Revisor |
| 905 ## - LOCAL DATA ELEMENT E, LDE (RLIN) | |
| Cataloger | Shimaa |
| Reviser | Cataloger |
| 942 ## - ADDED ENTRY ELEMENTS (KOHA) | |
| Source of classification or shelving scheme | Dewey Decimal Classification |
| Koha item type | Thesis |
| Source of classification or shelving scheme | Not for loan | Home library | Current library | Date acquired | Full call number | Barcode | Date last seen | Koha item type | Copy number |
|---|---|---|---|---|---|---|---|---|---|
| Dewey Decimal Classification | المكتبة المركزبة الجديدة - جامعة القاهرة | قاعة الرسائل الجامعية - الدور الاول | 11.02.2024 | Cai01.12.09.Ph.D.2020.Ah.S | 01010110082286000 | 22.09.2023 | Thesis | ||
| Dewey Decimal Classification | المكتبة المركزبة الجديدة - جامعة القاهرة | مخـــزن الرســائل الجـــامعية - البدروم | 11.02.2024 | Cai01.12.09.Ph.D.2020.Ah.S | 01020110082286000 | 22.09.2023 | CD - Rom | 82286.CD |