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003 EG-GiCUC
005 20250223032056.0
008 181008s2018 ua dh f m 000 0 eng d
040 _aEG-GiCUC
_beng
_cEG-GiCUC
041 0 _aeng
049 _aDeposite
097 _aM.Sc
099 _aCai01.12.10.M.Sc.2018.Ga.S
100 0 _aGamal Mohamed Zain Ahmed
245 1 0 _aSynthesis and characterization of superabsorbents based on modified starch for improving water and saline absorbency /
_cGamal Mohamed Zain Ahmed ; Superised Fawzy Ali Attabi , Ahmed Ibrahim waly
246 1 5 _aتحضير وتوصيف بوليمرات هيدرولوجيلية مبنية على النشا المحور لتحسين امتصاص الماء والمحاليل المائية
260 _aCairo :
_bGamal Mohamed Zain Ahmed ,
_c2018
300 _a103 P. :
_bcharts , facsimiles ;
_c25cm
502 _aThesis (M.Sc.) - Cairo University - Faculty of Science - Department of Organic Chemistry
520 _aNew starch derivatives containing sulfonated functional groups were prepared through intermediate triazinyl compounds. Four different bridging compounds were synthesized and characterized via spectral analysis. The sulfonated triazinyl compounds were reacted with native starch to obtain different density of sulfonic acid groups on starch backbone. The sulfonic acid groups were introduced in different degree of substitutions (0.043, 0.032, 0.006 and 0.008). A new amphoteric superabsorbent based on sodium starch sulfonate (SSS) is prepared by an indirect method. The sodium starch sulfonate was then graft-polymerized with acrylonitrile and the nitrile groups of the sodium starch sulfonate -g-polyacrylonitrile were converted to a mixture of hydrophilic carboxamide and carboxylate groups by alkaline hydrolysis. Optimum conditions of the co-polymerization were studied and recorded for 120 min polymerization time, 0.75% Ammonium persulfate (APS) associated with sodium bisulfite (50% of APS), 65oC for polymerization temperature and double molar ratio of acrylonitrile to the starch derivatives. The grafted acrylonitrile and the saponified products were spectrally characterized. The hydrogel based on the sulfonated starch derivatives showed superior water absorbency for both distilled and saline solutions over that of native starch
530 _aIssued also as CD
653 4 _aModified starch for improving water
653 4 _aSaline absorbency
653 4 _aSuperabsorbents based
700 0 _aAhmed Ibrahim waly ,
_eSupervisor
700 0 _aFawzy Ali Attabi ,
_eSupervisor
856 _uhttp://172.23.153.220/th.pdf
905 _aNazla
_eRevisor
905 _aShimaa
_eCataloger
942 _2ddc
_cTH
999 _c67866
_d67866