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003 EG-GiCUC
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008 190523s2018 ua h f m 000 0 eng d
040 _aEG-GiCUC
_beng
_cEG-GiCUC
041 0 _aeng
049 _aDeposite
097 _aM.Sc
099 _aCai01.12.10.M.Sc.2018.Mo.S
100 0 _aMohsen Elsayed Mohamed Amer
245 1 0 _aSynthesis, characterization and application of polymer nanoparticles based on gelatin graft copolymers /
_cMohsen Elsayed Mohamed Amer ; Supervised Magdy Sabaa Wadid Farag Sabaa , Soliman Mehawed Abdellatif Soliman
246 1 5 _aتحضير و توصيف و تطبيق جسيمات بوليميرية نانوية معتمدة على البلمرة المشاركة بالتطعيم للجيلاتين
260 _aCairo :
_bMohsen Elsayed Mohamed Amer ,
_c2018
300 _a85 P. :
_bfacsimiles ;
_c25cm
502 _aThesis (M.Sc.) - Cairo University - Faculty of Science - Department of Organic Chemistry
520 _aGelatin was chemically modified using grafting technique by vinyl monomers. Firstly, acrylonitrile was polymerized using controlled polymerization technique which is single electron transfer-living radical polymerization technique (SET-LRP) in presence of CCl4 as initiator. The Prepared poly(acrylonitrile) (PAN) has reactive end function as chloride group (-CH-Cl). The Prepared PAN-Cl has been grafted onto gelatin to obtain amphiphilic copolymer Gel-g-PAN. The copolymer was characterized using quantitative FTIR and 1H NMR spectroscopy, solubility and thermogravimetric analyses. Finally, nanoparticles based on prepared Gel-g-PAN were formed through nanoprecipitation technique and characterized by Transmission electron microscope (TEM). Different applications were tested for formed nanoparticles like metal ions and dye uptake and also encapsulation of hydrophobic model. Secondly, chemical modification of gelatin has been done through grafting using N-vinylimidazole (NVI). The kinetic parameters of grafting process included monomer concentration, initiator concentration and reaction temperature and time were studied. The grafting parameters such as thepercent graft yield (% G), percent graft efficiency (% GE) and percenthomopolymer (% H) were calculated and determined optimum conditions for grafting process
530 _aIssued also as CD
653 4 _aGelatin
653 4 _aGrafting
653 4 _aSET-LRP
700 0 _aMagdy Sabaa Wadid Farag Sabaa ,
_eSupervisor
700 0 _aSoliman Mehawed Abdellatif Soliman ,
_eSupervisor
856 _uhttp://172.23.153.220/th.pdf
905 _aNazla
_eRevisor
905 _aSamia
_eCataloger
942 _2ddc
_cTH
999 _c72135
_d72135