000 02585cam a2200349 a 4500
003 EG-GiCUC
005 20250223032306.0
008 190523s2018 ua d f m 000 0 eng d
040 _aEG-GiCUC
_beng
_cEG-GiCUC
041 0 _aeng
049 _aDeposite
097 _aM.Sc
099 _aCai01.12.10.M.Sc.2018.Ne.E
100 0 _aNesma Emad Mahmoud Mohemed
245 1 0 _aEffect of including extra phenylazo moiety on the mesophase behavior of three-ring azo/ester molecules /
_cNesma Emad Mahmoud Mohemed ; Supervised Abelgawad A. Fahmi , Magdi M. Naoum , Gamal R. Saad
246 1 5 _aتأثير ادخال مجموعه الفنيل أزو علي سلوك طور الوسط لمركبات الأزو/ أستر ثلاثيه الحلقة
260 _aCairo :
_bNesma Emad Mahmoud Mohemed ,
_c2018
300 _a104 P. :
_bcharts ;
_c25cm
502 _aThesis (M.Sc.) - Cairo University - Faculty of Science - Department of Organic Chemistry
520 _aFive homologous series of the four-ring 4-substituted phenylazo phenyl 4'-(4"-alkoxy phenylazo) benzoates (Ina-e) were prepared and their mesophase behavior investigated by differential scanning calorimetry (DSC) and identified by polarized light microscopy (PLM). Compounds prepared were structurally characterized via infrared, 1H-NMR, mass spectroscopy, thermogravimetric and elemental analysis. Transition temperatures were first correlated with the alkoxy-chain length (n, that varies between 6, 8, 10, 14, and 16 carbons) within each homologous series, and again with the polarisability anisotropy (xÜX) of the Ar-X bond, where X changes between CH3O, CH3, H, Br, and CN groups .Comparative studies were made to investigate the effect of introducing the extra phenyl azo moiety into the previously investigated three-ring compounds, 4-substituted phenyl 4{u2032}-(4{u2033}-alkoxyphenylazo) benzoates (IIna-e), 4-substituted phenylazo 4{u2032}-(4{u2033}- alkoxy phenyl) benzoates (IIIna-e), and 4-(4{u2032}-alkoxy phenylazo) phenyl 4{u2033}-substituted benzoates (IVna-e), each bear the same polar group, X, and the alkoxy group with chain length, n
530 _aIssued also as CD
653 4 _a4-substituted phenylazo phenyl 4'-(4"-alkoxy phenylazo) benzoates
653 4 _aMesophase stability
653 4 _aThermal stability
700 0 _aAbelgawad A. Fahmi ,
_eSupervisor
700 0 _aGamal R. Saad ,
_eSupervisor
700 0 _aMagdi M. Naoum ,
_eSupervisor
856 _uhttp://172.23.153.220/th.pdf
905 _aAsmaa
_eCataloger
905 _aNazla
_eRevisor
942 _2ddc
_cTH
999 _c72147
_d72147