000 02246cam a2200337 a 4500
003 EG-GiCUC
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008 190525s2018 ua d f m 000 0 eng d
040 _aEG-GiCUC
_beng
_cEG-GiCUC
041 0 _aeng
049 _aDeposite
097 _aM.Sc
099 _aCai01.12.20.M.Sc.2018.Di.C
100 0 _aDina Ali Sayed Abdelgawad
245 1 0 _aCharacterization of some new organic-inorganic hybrids /
_cDina Ali Sayed Abdelgawad ; Supervised Mohga Farid Mostafa , Ahmed Kamel Mohamed
246 1 5 _aتحديد الخصائص لبعض المهجنات العضوية- غير العضوية
260 _aCairo :
_bDina Ali Sayed Abdelgawad ,
_c2018
300 _a101 P. :
_bcharts ;
_c25cm
502 _aThesis (M.Sc) - Cairo University - Faculty of Science - Department of Physics
520 _aThe aim of this work is to study structural, thermal, dielectric properties and conductivity of new organic-inorganic hybrids. Results were acquired for two different alkylene-diammonium divalent metal hybrids with chemical formula [(CH₂) (NH₃ )₂ ]MCl₄ . The first has n=7 and M= Ca²⁺ (non-magnetic alkaline earth element), and the second has longer chain n=8 and M=Co²⁺ (a magnetic ion). Powder X-ray diffraction of Ca-hybrid indicated a monoclinic structure (sp.gp. Pm) with a=4.625 {u1EB2}, b= 11.205 {u1EB2}, c= 12.391 {u1EB2} and Ý= 86.82 o, Z= 2, d= 1.63 gm/cm³, V= 641.2 {u1EB2}³. Co-hybrid revealed a triclinic system (sp.gp. P1{u00AF}) with a = 8.368 {u01FA}, b = 12.888 {u01FA}, c = 15.045 {u01FA} and Ü=97.56{u00BA}, Ý= 86.82{u00BA}, Þ=89.82{u00BA}, Z=4, d=1.44 gm/cm³, V= 1597.3{u01FA}³. Thermal measurements showed five phase transitions in the temperature range (260 K-330 K) for Ca and three for Co-hybrid in the temperature range (300 K-420 K). These transitions are reflected in the dielectric behavior
530 _aIssued also as CD
653 4 _aAc conductivity
653 4 _aHybrids
653 4 _aPowder X-ray diffraction
700 0 _aAhmed Kamel Mohamed ,
_eSupervisor
700 0 _aMohga Farid Mostafa ,
_eSupervisor
856 _uhttp://172.23.153.220/th.pdf
905 _aAsmaa
_eCataloger
905 _aNazla
_eRevisor
942 _2ddc
_cTH
999 _c72158
_d72158