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003 EG-GiCUC
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008 190902s2019 ua d f m 000 0 eng d
040 _aEG-GiCUC
_beng
_cEG-GiCUC
041 0 _aeng
049 _aDeposite
097 _aM.Sc
099 _aCai01.12.10.M.Sc.2019.Is.S
100 0 _aIslam Mohammed Ahmed Ismael
245 1 0 _aSynthesis and characterization of ion exchanger based on waste cotton for dye removal from wastewater /
_cIslam Mohammed Ahmed Ismael ; Supervised Bahia Yehia Riad , Maaly Abdelmoneim Khedr , Hyman Hassan Mohamed Rehan
246 1 5 _aتحضير وتوصيف مبادل ايوني مبني على عوادم الألياف القطنية لإزالة الصبغات من المخلفات السائلة
260 _aCairo :
_bIslam Mohammed Ahmed Ismael ,
_c2019
300 _a133 P. :
_bcharts ;
_c25cm
502 _aThesis (M.Sc.) - Cairo University - Faculty of Science - Department of Organic Chemistry
520 _aPolymerization of glycidyl methacrylate (GMA) with waste cotton fabric using a ferrous cellulose thiocarbonate{u2013}hydrogen peroxide redox system as a coinitiator was first investigated under different conditions. These include the polymerization time, temperature, liquor ratio, pH and concentrations of the initiator and monomer. The product cellulose-poly(glycidyl methacrylate) graft copolymer (Cell-g-PGMA)- produced at best polymerization conditions- was then functionalized with four different amines, namely, tri-ethyl-amine hydrochloride (TEAC), diethylene-tri-amine (DETA), tri-ethylene-tetra-amine (TETA), aiming to obtain a low-cost adsorbent for dye removal from wastewater. Factors affecting the aminization reaction, specifically the reaction time, temperature, liquor ratio, pH, and aminating agent/epoxy molar ratio, were also studied. The prepared amino-functionalized cellulose-poly(glycidyl methacrylate) graft copolymer (AM-Cell-g-PGMA) was further analyzed for epoxy and nitrogen content, and also characterized by the Fourier-transform infrared spectroscopy(FT-IR), thermal gravimetric analysis (TGA), scanning electron microscope (SEM) and surface area measurement based on Brunauer{u2013} Emmett{u2013}Teller (BET) and Barrett-Joyner-Halenda (BJH) theories. The adsorption of two dyes (C.I. Acid black 194 and C.I Reactive black 5) onto the prepared anion exchangers was then investigated at different conditions such as adsorption time, pH, temperature and initial dye concentration, at different temperature values. The different isotherm and kinetic models of the adsorption of the two dyes onto the prepared anion exchange were also examined
530 _aIssued also as CD
653 4 _aAdsorbents
653 4 _aCotton fibers
653 4 _aWastewater
700 0 _aBahia Yehia Riad ,
_eSupervisor
700 0 _aHyman Hassan Mohamed Rehan ,
_eSupervisor
700 0 _aMaaly Abdelmoneim Khedr ,
_eSupervisor
856 _uhttp://172.23.153.220/th.pdf
905 _aAsmaa
_eCataloger
905 _aNazla
_eRevisor
942 _2ddc
_cTH
999 _c73596
_d73596