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003 EG-GiCUC
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008 220202s2021 ua dh f m 000 0 eng d
040 _aEG-GiCUC
_beng
_cEG-GiCUC
041 0 _aeng
049 _aDeposite
097 _aM.Sc
099 _aCai01.12.09.M.Sc.2021.Ah.C
100 0 _aAhmed Eissawy Saleh Eissawy
245 1 0 _aCharacterization and different applications of some schiff bases metal complexes /
_cAhmed Eissawy Saleh Eissawy ; Supervised Gehad Genidy Mohamed , Walaa Hamed Mahmoud , Reem Gamal Deghadi
246 1 5 _aتوصيف وتطبيقات مختلفة لبعض المتراكبات الفلزية لقواعد شيف
260 _aCairo :
_bAhmed Eissawy Saleh Eissawy ,
_c2021
300 _a185 P . :
_bcharts , facsmilies ;
_c25cm
502 _aThesis (M.Sc.) - Cairo University - Faculty of Science - Department of Inorganic Chemistry
520 _aSchiff bases and their metal complexes are compounds that can be used for industrial purposes as corrosion inhibitors and catalytic activity and also show a broad range of biological activities including antibacterial, antifungal, antiviral, antimalarial ,anti-inflammatory, anticancer, anti-HIV, and antipyretic properties. In the light of that, two novel Schiff bases namely 1-(6-(1-((4-(4-aminophenoxy)phenyl)imino)ethyl)pyridin-2-yl)ethan-1-one (L1) and 4-(4-((1-(pyridine-2-yl)ethylidene)-amino)phenoxy)aniline (L2) and their complexes with Cr(III), Mn(II), Fe(III), Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) metal ions were produced and characterized by elemental analyses, mass spectrometry, FT-IR, 1H NMR, molar conductance, and thermal analyses techniques (TG and DTG). The chelates were found to have octahedral geometry. The in vitro antibacterial activity of the ligands and their complexes were also screened. Computational studies of the two Schiff bases ligands had been carried out using DFT/B3LYP method. Molecular docking studies were investigated between the prepared compounds and different protein receptors. The anticorrosion activities of two synthesized Schiff bases (L1 and L2) were evaluated by different electrochemical techniques and confirmed by SEM and EDX
530 _aIssued also as CD
653 4 _aDFT
653 4 _aSchiff base complexes
653 4 _aThermal analyses (TG and DTG)
700 0 _aGehad Genidy Mohamed ,
_eSupervising
700 0 _aReem Gamal Deghadi ,
_eSupervising
700 0 _aWalaa Hamed Mahmoud ,
_eSupervising
856 _uhttp://172.23.153.220/th.pdf
905 _aAmira
_eCataloger
905 _aNazla
_eRevisor
942 _2ddc
_cTH
999 _c84091
_d84091