Some organometallic schiff base metal complexes : (Record no. 75265)
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| 000 -LEADER | |
|---|---|
| fixed length control field | 02921cam a2200337 a 4500 |
| 003 - CONTROL NUMBER IDENTIFIER | |
| control field | EG-GiCUC |
| 005 - DATE AND TIME OF LATEST TRANSACTION | |
| control field | 20250223032440.0 |
| 008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION | |
| fixed length control field | 191117s2019 ua h f m 000 0 eng d |
| 040 ## - CATALOGING SOURCE | |
| Original cataloging agency | EG-GiCUC |
| Language of cataloging | eng |
| Transcribing agency | EG-GiCUC |
| 041 0# - LANGUAGE CODE | |
| Language code of text/sound track or separate title | eng |
| 049 ## - LOCAL HOLDINGS (OCLC) | |
| Holding library | Deposite |
| 097 ## - Thesis Degree | |
| Thesis Level | Ph.D |
| 099 ## - LOCAL FREE-TEXT CALL NUMBER (OCLC) | |
| Classification number | Cai01.12.09.Ph.D.2019.Fa.S |
| 100 0# - MAIN ENTRY--PERSONAL NAME | |
| Personal name | Fatma Nabil Sayed Hussein |
| 245 10 - TITLE STATEMENT | |
| Title | Some organometallic schiff base metal complexes : |
| Remainder of title | Preparation, characterization and applications / |
| Statement of responsibility, etc. | Fatma Nabil Sayed Hussein ; Supervised Mohamed Mohamed Omar , Walaa Hamed Mahmoud |
| 246 15 - VARYING FORM OF TITLE | |
| Title proper/short title | بعض متراكبات قواعد شيف العضوفلزية : |
| Remainder of title | تحضير: توصيف و تطبيقات |
| 260 ## - PUBLICATION, DISTRIBUTION, ETC. | |
| Place of publication, distribution, etc. | Cairo : |
| Name of publisher, distributor, etc. | Fatma Nabil Sayed Hussein , |
| Date of publication, distribution, etc. | 2019 |
| 300 ## - PHYSICAL DESCRIPTION | |
| Extent | 358 P. : |
| Other physical details | facsimiles ; |
| Dimensions | 25cm |
| 502 ## - DISSERTATION NOTE | |
| Dissertation note | Thesis (Ph.D.) - Cairo University - Faculty of Science - Department of Inorganic Chemistry |
| 520 ## - SUMMARY, ETC. | |
| Summary, etc. | This work had been done to investigate the coordination behavior of five newly synthesized organometallic schiff bases derived from condensation of 2- acetylferrocene with 2-aminothiophenol, 3-aminophenol, 1,3-diaminopropane, tris (2- aminoethyl) amine and L-histidine, towards some transition metal ions such as Cr(III), Mn(II), Fe(III), Co(II), Ni(II), Cu(II), Zn(II) and Cd(II). The organometallic ligands and their solid chelates were prepared and characterized by different analytical techniques such as elemental analyses, mass spectrometry, IR, 1H NMR, UV-Vis., molar conductance, SEM and thermal analyses techniques. SEM showed that Cd(II)- (HL1) complex had the smallest nanosize particle (15.69 nm) The molecular and electronic structure of the free ligands were optimized theoretically, and the quantum chemical parameters were calculated. The molecular structure can be used to investigate the coordination sites and the total charge density around each atom using the Gaussian03 suite of programs. The structures were fully optimized employing the DFT-based B3LYP method along with the LANL2DZ basis set. The biological activity (antimicrobial and anticancer activity) of the newly synthesized ligands and their metal chelates were also screened. It was found that HL1 had the highest antifungal activity (18 mm) against A. fumigatus fungus, Co(II)-L5 complex had the highest antibacterial activity (21 mm) against S. typhimurium gram -ve bacteria and Cd(II)-L5 complex had the lowest IC50 at all (3.50 og/ml). Molecular docking was used to predict the binding between the free ligands and some metal chelates with different proteins using MOE 2008 software |
| 530 ## - ADDITIONAL PHYSICAL FORM AVAILABLE NOTE | |
| Additional physical form available note | Issued also as CD |
| 653 #4 - INDEX TERM--UNCONTROLLED | |
| Uncontrolled term | Organometallic |
| 653 #4 - INDEX TERM--UNCONTROLLED | |
| Uncontrolled term | SEM |
| 653 #4 - INDEX TERM--UNCONTROLLED | |
| Uncontrolled term | UV-Vis |
| 700 0# - ADDED ENTRY--PERSONAL NAME | |
| Personal name | Mohamed Mohamed Omar , |
| Relator term | |
| 700 0# - ADDED ENTRY--PERSONAL NAME | |
| Personal name | Walaa Hamed Mahmoud , |
| Relator term | |
| 856 ## - ELECTRONIC LOCATION AND ACCESS | |
| Uniform Resource Identifier | <a href="http://172.23.153.220/th.pdf">http://172.23.153.220/th.pdf</a> |
| 905 ## - LOCAL DATA ELEMENT E, LDE (RLIN) | |
| Cataloger | Nazla |
| Reviser | Revisor |
| 905 ## - LOCAL DATA ELEMENT E, LDE (RLIN) | |
| Cataloger | Samia |
| Reviser | Cataloger |
| 942 ## - ADDED ENTRY ELEMENTS (KOHA) | |
| Source of classification or shelving scheme | Dewey Decimal Classification |
| Koha item type | Thesis |
| Source of classification or shelving scheme | Not for loan | Home library | Current library | Date acquired | Full call number | Barcode | Date last seen | Koha item type | Copy number |
|---|---|---|---|---|---|---|---|---|---|
| Dewey Decimal Classification | المكتبة المركزبة الجديدة - جامعة القاهرة | قاعة الرسائل الجامعية - الدور الاول | 11.02.2024 | Cai01.12.09.Ph.D.2019.Fa.S | 01010110079946000 | 22.09.2023 | Thesis | ||
| Dewey Decimal Classification | المكتبة المركزبة الجديدة - جامعة القاهرة | مخـــزن الرســائل الجـــامعية - البدروم | 11.02.2024 | Cai01.12.09.Ph.D.2019.Fa.S | 01020110079946000 | 22.09.2023 | CD - Rom | 79946.CD |