000			02517cam a2200337 a 4500
003			EG-GiCUC
005			20250223031213.0
008			150414s2014 ua d f m 000 0 eng d
040			_aEG-GiCUC _beng _cEG-GiCUC
041	0		_aeng
049			_aDeposite
097			_aPh.D
099			_aCai01.12.08.Ph.D.2014.Sa.A
100	0		_aSattar Rajab Majeed Alessawi
245	1	0	_aAnalytical and inorganic studies of new antitumor palladium (II), ruthenium II) and platinum (IV) complexes / _cSattar Rajab Majeed Alessawi ; Supervised Ahmed Soliman Abdellah , Fawzy Ali Attaby
246	1	5	_aدراسات تحليلية وغير عضوية لمعقدات البلاديوم والثنائى والروثينيوم الثنائى والبلاتين الرباعى كمضادات جديدة للأورام
260			_aCairo : _bSattar Rajab Majeed Alessawi , _c2014
300			_a320 P. : _bcharts ; _c25cm
502			_aThesis (Ph.D.) - Cairo University - Faculty of Science - Department of Analytical Chemistry
520			_aFive rapid, simple, sensitive and validated spectrophotometric method has been described for the determination of palladium(II) using 3,4diaminobenzoic acid(DABA)(1),4-chloro{u2013}o-phenylenediamine (CPDA)(2) and 2-hydrazino pyridine (hzpy)(3) and both ruthenium(III)(4) and platinum(IV)(5) using 4-chloro{u2013}o-phenylenediamine(CPDA). The complexes product was quantitatively measured at 760 nm(1), 545nm(2), 510 nm(3), 560nm(4) and 715nm(5) and the reaction conditions were studied and optimized. The stoichiometry and the stability constant of the purple colored complexes have been determined spectrophotometrically in aqueous solution at 25 oC using Job{u2019}s continuous variation and the molar ratio methods. The complexes have The molar ratios (M:L) : 1:2(1), 1:2(2), 1:1(3), 1:1(4),1:2(5) and Beer{u2019}s plot was linear in the concentration ranges 1.06- 8.48(1), 2.21-10.6(2), 1.06-9.00(3), 2.00-12,36(4) and 1.95-27.30(5) og/mL with corresponding molar absorptivity 1.32{u00D7}10⁴(1), 2.89{u00D7}10³(2), 2.60{u00D7}10³(3), 1.91{u00D7}10³, 2.13{u00D7}10³(5) , L/mol.cm
530			_aIssued also as CD
653		4	_a2- hydraziniopyridin Pt(IV)
653		4	_a3,4-diaminobinzoic
653		4	_a4-chloro-o-phyelenediamin
700	0		_aAhmed Soliman Abdellah , _eSupervisor
700	0		_aFawzy Ali Attaby , _eSupervisor
856			_uhttp://172.23.153.220/th.pdf
905			_aAml _eCataloger
905			_aNazla _eRevisor
942			_2ddc _cTH
999			_c50416 _d50416