000 | 02595cam a2200337 a 4500 | ||
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003 | EG-GiCUC | ||
005 | 20250223031905.0 | ||
008 | 171226s2017 ua do f m 000 0 eng d | ||
040 |
_aEG-GiCUC _beng _cEG-GiCUC |
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041 | 0 | _aeng | |
049 | _aDeposite | ||
097 | _aPh.D | ||
099 | _aCai01.12.09.Ph.D.2017.Ne.P | ||
100 | 0 | _aNessma Fathy Erian Mahmoud | |
245 | 1 | 0 |
_aPhysicochemical studies on schiff base ligands derived from acetyl ferrocene with some transition metal ions / _cNessma Fathy Erian Mahmoud ; Supervised Gehad Genidy Mohamed , Walaa Hamed Mahmoud |
246 | 1 | 5 | _aدراسات فيزوكيميائية على ليجندات قاعدة شيف مشتقة من أسيتايل فيروسين مع بعض أيونات العناصر الإنتقالية |
260 |
_aCairo : _bNessma Fathy Erian Mahmoud , _c2017 |
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300 |
_a320 P. : _bcharts , photographs ; _c25cm |
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502 | _aThesis (Ph.D.) - Cairo University - Faculty of Science - Department of Inorganic Chemistry | ||
520 | _aThe coordination chemistry of some transition metal ions and some lanthanides metal ions with two mononegative bidentate ferrocene based Schiff base ligands HL (HL₁ and HL₂) (as primary ligand) and 1,10-phenanthroline (as secondary ligand) were elucidated. The HL₁ ligand was prepared from condensation between 2-acetyl ferrocene and anthranilic acid, but HL₂ was prepared from condensation between ferrocene and 2-aminophenol. The metal complexes were characterized by elemental analyses, molar conductance, IR, 1H NMR, UV-Visible, mass spectroscopy, SEM and thermal analyses techniques (TG/DTG). DFT-based molecular orbital energy calculations of the new ligands have been also studied. The HL ligands (HL₁ and HL₂) were bidentately coordinating via the nitrogen atom of azomethine group and oxygen of deprotonated carboxylic group of HL and in case of HL₂ by deprotonated phenolic group. The HL₁ ligands (HL₁ and HL₂) and their binary and mixed ligand chelates were subjected to thermal analyses (TG and DTG). The biological activity (antimicrobial and antibreastic cancer activity) was also screened. MOE (molecular operating environment docking studies were performed using MOE 2008 software | ||
530 | _aIssued also as CD | ||
653 | 4 | _aElemental analyses | |
653 | 4 | _aMolar conductance | |
653 | 4 | _aThermal analyses | |
700 | 0 |
_aGehad Genidy Mohamed , _eSupervisor |
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700 | 0 |
_aWalaa Hamed Mahmoud , _eSupervisor |
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856 | _uhttp://172.23.153.220/th.pdf | ||
905 |
_aNazla _eRevisor |
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905 |
_aSamia _eCataloger |
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942 |
_2ddc _cTH |
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999 |
_c64278 _d64278 |