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003 EG-GiCUC
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008 171226s2017 ua do f m 000 0 eng d
040 _aEG-GiCUC
_beng
_cEG-GiCUC
041 0 _aeng
049 _aDeposite
097 _aPh.D
099 _aCai01.12.09.Ph.D.2017.Ne.P
100 0 _aNessma Fathy Erian Mahmoud
245 1 0 _aPhysicochemical studies on schiff base ligands derived from acetyl ferrocene with some transition metal ions /
_cNessma Fathy Erian Mahmoud ; Supervised Gehad Genidy Mohamed , Walaa Hamed Mahmoud
246 1 5 _aدراسات فيزوكيميائية على ليجندات قاعدة شيف مشتقة من أسيتايل فيروسين مع بعض أيونات العناصر الإنتقالية
260 _aCairo :
_bNessma Fathy Erian Mahmoud ,
_c2017
300 _a320 P. :
_bcharts , photographs ;
_c25cm
502 _aThesis (Ph.D.) - Cairo University - Faculty of Science - Department of Inorganic Chemistry
520 _aThe coordination chemistry of some transition metal ions and some lanthanides metal ions with two mononegative bidentate ferrocene based Schiff base ligands HL (HL₁ and HL₂) (as primary ligand) and 1,10-phenanthroline (as secondary ligand) were elucidated. The HL₁ ligand was prepared from condensation between 2-acetyl ferrocene and anthranilic acid, but HL₂ was prepared from condensation between ferrocene and 2-aminophenol. The metal complexes were characterized by elemental analyses, molar conductance, IR, 1H NMR, UV-Visible, mass spectroscopy, SEM and thermal analyses techniques (TG/DTG). DFT-based molecular orbital energy calculations of the new ligands have been also studied. The HL ligands (HL₁ and HL₂) were bidentately coordinating via the nitrogen atom of azomethine group and oxygen of deprotonated carboxylic group of HL and in case of HL₂ by deprotonated phenolic group. The HL₁ ligands (HL₁ and HL₂) and their binary and mixed ligand chelates were subjected to thermal analyses (TG and DTG). The biological activity (antimicrobial and antibreastic cancer activity) was also screened. MOE (molecular operating environment docking studies were performed using MOE 2008 software
530 _aIssued also as CD
653 4 _aElemental analyses
653 4 _aMolar conductance
653 4 _aThermal analyses
700 0 _aGehad Genidy Mohamed ,
_eSupervisor
700 0 _aWalaa Hamed Mahmoud ,
_eSupervisor
856 _uhttp://172.23.153.220/th.pdf
905 _aNazla
_eRevisor
905 _aSamia
_eCataloger
942 _2ddc
_cTH
999 _c64278
_d64278