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008 190219s2018 ua d f m 000 0 eng d
040 _aEG-GiCUC
_beng
_cEG-GiCUC
041 0 _aeng
049 _aDeposite
097 _aM.Sc
099 _aCai01.08.04.M.Sc.2018.Sh.S
100 0 _aShimaa Magdy Ibrahim Alhamaky
245 1 0 _aSynthesis of new pyrazoles as anti-inflammatory agents /
_cShimaa Magdy Ibrahim Alhamaky ; Supervised Mohamed A. Shaaban , Ashraf F. Zaher , Lamia W. Mohamed
246 1 5 _aتشييد مشتقات بيرازول جديدة كعوامل مضادة للالتهاب
260 _aCairo :
_bShimaa Magdy Ibrahim Alhamaky ,
_c2018
300 _a97 P. :
_bcharts ;
_c25cm
502 _aThesis (M.Sc.) - Cairo University - Faculty of Pharmacy - Department of Organic Chemistry
520 _aThis thesis includes four chapters in addition to references and arabic summary. The first chapter is the introduction, which consist of a brief literature survey of the synthesis and reactions of pyrazoles. It also involve an account on the anti-inflammatory agents. The second chapter involves the objectives of this work based on structure activity relationship and molecular modelling study. It also demonstrates the schemes of synthesis of the new derivatives. The third chapter clarifies the theoretical discussion of the experimental work used to synthesis in addition to spectroscopic data of the starting materials I , II and the target new compounds IIIa-f, IVa-L, Va-f. The fourth chapter is divided in to three parts representing the experimental part of the thesis. The first part is the synthetic approach that comprises the detailed methods for preparation of designed compounds in three schemes. Scheme I : includes synthesis of I followed by reaction with o-fluoro aniline affording derivative II. This was followed by coupling with diazotized aromatic amines in ethanol in presence of sodium acetate to afford IIIa-f. Scheme II : involves the mannich procedure for the reaction of IIIa-f with anilin or 2,6-dimethyl aniline and 40% formaldehyde in ethanol at 60 oC to afford IVa-L. Scheme III: involves the synthesis of Va-f by cyclization reaction of II with appropriate aromatic aldehydes and malononitrl in ethanol containing ammonium acetate
530 _aIssued also as CD
653 4 _aMannich reaction
653 4 _aPyrazoles
653 4 _aPyrazolopyridine
700 0 _aAshraf Fouad Zaher ,
_eSupervisor
700 0 _aLamia Wagdy Mohamed ,
_eSupervisor
700 0 _aMohamed Abdelrahman Shaaban ,
_eSupervisor
856 _uhttp://172.23.153.220/th.pdf
905 _aNazla
_eRevisor
905 _aSamia
_eCataloger
942 _2ddc
_cTH
999 _c70343
_d70343