000 02644cam a2200337 a 4500
003 EG-GiCUC
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008 190911s2018 ua dho f m 000 0 eng d
040 _aEG-GiCUC
_beng
_cEG-GiCUC
041 0 _aeng
049 _aDeposite
097 _aPh.D
099 _aCai01.12.11.Ph.D.2018.Ad.P
100 0 _aAdel Ali Abdelkader
245 1 0 _aPreparation of carbon nanotubes over mixed metal-oxide catalysts /
_c Adel Ali Abdelkader ; Supervised Gamal R. Saad , Mustafa M. Kamel
246 1 5 _aتحضير انابيب الكربون النانومترية فوق محفزات مختلطة من اكاسيد المعادن
260 _aCairo :
_bAdel Ali Abdelkader ,
_c2018
300 _a95 P. :
_bcharts , facsimiles , photographs ;
_c25cm
502 _aThesis (Ph.D.) - Cairo University - Faculty of Science - Department of Physical Chemistry
520 _aCatalytic chemical vapor deposition (CCVD) is one of the most promising synthesis methods for economically producing large quantities of different nanocarbon structures. This study is focused on the synthesis of different morphological structures of carbon nanotubes via acetylene decomposition over the surface of quaternary-metallic catalyst (Fe-Ni-Co-Mo) supported on MgO (Fe-Ni-Co-Mo/MgO). In this study, different growth parameters, such as catalyst pretreatment atmosphere, carrier gas, carbon precursor, temperature, and reaction time were investigated to optimize the yield, quality, size, purity and graphitic crystallinity of the deposited carbon. The obtained samples were characterized by high resolution transmission electron microscopy (HR-TEM), thermogravimetric analysis (TGA), Raman spectroscopy, FTIR and X-ray diffraction. TEM images and Raman spectra of samples showed, depending on the conditions of deposit carbon, showed a successful synthesis of carbon nanobud, Onion-like (O-CNT) structure, a high-yield and quality bamboo-like multiwalled carbon nanotubes (b-CNT), hybrid graphene/carbon nanotubes (G/CNT) and multilayer graphene (MLG). TGA analysis showed no evidence of carbonaceous materials is formed during the synthesis process. The results found seem essential for realizing the role of different synthesis parameters on the yield, quality, and morphology of the synthesized product
530 _aIssued also as CD
653 4 _aCarbon nanotubes
653 4 _aCCVD
653 4 _aGraphene
700 0 _aGamal R. Saad ,
_eSupervisor
700 0 _aMustafa M. Kamel ,
_eSupervisor
856 _uhttp://172.23.153.220/th.pdf
905 _aAsmaa
_eCataloger
905 _aNazla
_eRevisor
942 _2ddc
_cTH
999 _c73803
_d73803