000 02331cam a2200337 a 4500
003 EG-GiCUC
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008 200831s2020 ua dh f m 000 0 eng d
040 _aEG-GiCUC
_beng
_cEG-GiCUC
041 0 _aeng
049 _aDeposite
097 _aPh.D
099 _aCai01.12.10.Ph.D.2020.Ah.S
100 0 _aAhmed Mohamed Abdelfatah Refaie Sultan
245 1 0 _aSynthesis and structure property relationship of some organic azo compounds /
_cAhmed Mohamed Abdelfatah Refaie Sultan ; Supervised Abdelgawad Ali Fahmi , Magdi Naoum
246 1 5 _aتشييد وعلاقة التركيب بالخواص لبعض مركبات الآزو العضوية
260 _aCairo :
_bAhmed Mohamed Abdelfatah Refaie Sultan ,
_c2020
300 _a200 , (30) P. :
_bcharts , facsimiles ;
_c25cm
502 _aThesis (Ph.D.) - Cairo University - Faculty of Science - Department of Organic Chemistry
520 _aTwo homologous series of the three-ring azo/ester compounds 2-(or1-) naphthyl 4'-(4''-alkoxy phenylazo) benzoates (Ina and IIna) were synthesized and characterized for their thermal behavior in order to investigate the effect of orientation of the naphthyl group on the mesophase behavior. A lateral methyl group was introduced into different positions of the alkoxy phenyl moiety, in position-2 to give series Inb and IInb and in position-3 to give series Inc and IInc to study the effect of insertion of a lateral substituent on the mesomorphic behavior of the synthesized compounds. Molecular structures of all of the prepared compounds were characterized via elemental analyses, fourier-transform infrared spectroscopy and 1H-NMR sspectra.Their mesophase characteristics were investigated by differential scanning calorimetry (DSC) and their phases identified via polarized light microscopy (PLM).Transition temperatures were correlated with the alkoxychain length (n), that varies between 6, 8, 10, 12, 14, and 16 carbons
530 _aIssued also as CD
653 4 _aLateral methyl group
653 4 _aNaphthyl azo/ester liquid crystals
653 4 _aOrientation
700 0 _aAbdelgawad Ali Fahmi ,
_eSupervisor
700 0 _aMagdi Naoum ,
_eSupervisor
856 _uhttp://172.23.153.220/th.pdf
905 _aNazla
_eRevisor
905 _aShimaa
_eCataloger
942 _2ddc
_cTH
999 _c77471
_d77471