000 02365cam a2200337 a 4500
003 EG-GiCUC
005 20250223032626.0
008 201110s2020 ua dh f m 000 0 eng d
040 _aEG-GiCUC
_beng
_cEG-GiCUC
041 0 _aeng
049 _aDeposite
097 _aM.Sc
099 _aCai01.12.08.M.Sc.2020.Mo.E
100 0 _aMoustafa Mohamed Hassan Ali
245 1 0 _aElectrochemical sensors for determination of some metal ions in water samples /
_cMoustafa Mohamed Hassan Ali ; Supervised Fakiha Mohamed Eltaib Heakal , Marwa Elbadry Mohamed
246 1 5 _aمجسات كهروكيميائية لتقدير بعض أيونات الفلزات فى عينات مياه
260 _aCairo :
_bMoustafa Mohamed Hassan Ali ,
_c2020
300 _a112 P. :
_bcharts , facimiles ;
_c25cm
502 _aThesis (M.Sc.) - Cairo University - Faculty of Science - Department of Analytical Chemistry
520 _aThe present work aims to fabricate newly sensitive, fast and selective Al(III) ions electrochemical sensors based on CPEs chemically modified with diphenylcarbazone (DPC) ionophore and containing or not containing graphene nanosheets. The performance and characteristics of the sensors were discussed using potentiometric, cyclic voltammetric (CV) and electrochemical impedance spectroscopy (EIS) measurements. In the potentiometric method the linear concentration range of the proposed sensors was 1.0 oM to 10.0 mM with good Nernstian slope using two electrodes (I) and (II). Cyclic voltammetric method for Al(III) ions detection in Britton{u2013}Robinson buffer solution of pH 3.0 revealed a linear relationship between Ip and analyte concentration over a wide range from 10.0 mM down to 0.1 oM. These electrodes proved to be sensitive and selective for Al(III) ions determination in spiked tap water, pharmaceutical preparation and drainage wastewater samples. The physical characterization of these sensors was also investigated via SEM, EDX and FT- IR analyses
530 _aIssued also as CD
653 4 _aAl(III) ions
653 4 _aCarbon paste electrode
653 4 _aDiphenylcarbazone
700 0 _aFakiha Mohamed Eltaib Heakal ,
_eSupervisor
700 0 _aMarwa Elbadry Mohamed ,
_eSupervisor
856 _uhttp://172.23.153.220/th.pdf
905 _aNazla
_eRevisor
905 _aShimaa
_eCataloger
942 _2ddc
_cTH
999 _c78665
_d78665